Last Updated on December 17, 2020
Former Ambassadors
| S.No | Name | Year |
| 1 | Shri Sant Singh | Feb 1950 To Oct 1953 |
| 2 | Maj Gen. Hira Lal Atal | Dec 1953 To Dec 1954 |
| 3 | Shri N. S. Gill | Jan 1955 To Jan 1960 |
| 4 | Shri R. G. Rajwade | Oct 1960 To Oct 1962 |
| 5 | Shri J.K. Atal | Feb 1963 To Mar 1966 |
| 6 | Shri K.L.Mehta | Mar 1966 To Jun 1968 |
| 7 | Shri O.V.Alagesan | Aug 1968 To Aug 1971 |
| 8 | Shri K.C. Sen Gupta | Oct 1971 To Nov 1973 |
| 9 | Shri V.V.Paranjpe | Jun 1974 To Dec 1977 |
| 10 | Shri V.K.Verma | Dec 1977 To Sep 1980 |
| 11 | Shri P.K.Budhwar | Nov 1980 To Jul 1983 |
| 12 | Shri C.V. Ranganathan | Dec 1983 To Jul 1985 |
| 13 | Shri S.K. Arora | Oct 1985 To Jun 1989 |
| 14 | Shri K.P. Balakrishnan | Jul 1989 To Jun 1991 |
| 15 | Shri G.S. Bedi | Jul 1991 To Dec 1992 |
| 16 | Shri Gurucharan Singh | Dec 1992 To Mar 1997 |
| 17 | Shri K.P. Ernest | Jan 1998 To Apr 2001 |
| 18 | Smt Jordana Diengdoh Pavel | May 2002 To Aug 2005 |
| 19 | Shri Gurjit Singh | Sep 2005 To Aug 2009 |
| 20 | Shri Bhagwant Singh Bishnoi | Jan 2010 To Nov 2013 |
| 21 | Shri Sanjay Verma | Dec 2013 To Jan 2016 |
| 22 | Shri Anurag Srivastava | Sep 2016 To Mar 2020 |
| 23 | Shri Robert Shetkintong | Oct 2020 to Jan 2024 |
Former Permanent Representatives of India to the African Union
| S.No | Name | Year |
| 1 | Smt Jordana Diengdoh Pavel | Mar 2005 To Aug 2005 |
| 2 | Shri Gurjit Singh | Sep 2005 To Aug 2009 |
| 3 | Shri Bhagwant Singh Bishnoi | Jan 2010 To Nov 2013 |
| 4 | Shri Sanjay Verma | Dec 2013 To Jan 2016 |
| 5 | Shri Anurag Srivastava | Sep 2016 To Mar 2020 |
| 6 | Shri Robert Shetkintong | Oct 2020 to Jan 2024 |
